There is a list of HF Voice frequencies slowly coming together on the ‘CPDLC & SELCAL’ page of the site.
In short…
I look in every single L and C-Band ACARS message for either FACILITY DESIGNATION or FACILITY NAME and then pull the primary frequency and if its listed, the secondary.
The plan was simple, but it became very complicated as the same frequency is used used in different zones and the names/designations are not consistent (or helpful).
Consider it a work in progress.